Search results for "exciton-phonon interaction"

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Homogeneous and inhomogeneous broadening in single perovskite nanocrystals investigated by micro-photoluminescence

2021

Abstract Metal halides with perovskite crystalline structure have given rise to efficient optoelectronic and photonic devices. In the present work, we have studied the light emission properties of single CsPbBr3 and CsPbI3 semiconductor perovskite nanocrystals (PNCs), as the basis for a statistical analysis of micro-photoluminescence (micro-PL) spectra measured on tens of them. At room temperature, the linewidth extracted from PL spectra acquired in dense films of these nanocrystals is not very different from that of micro-PL measured in single nanocrystals. This means that the homogeneous linewidth due to exciton-phonon interaction is comparable or larger than the inhomogeneous effect asso…

Materials sciencebusiness.industryBiophysicsGeneral ChemistryCrystal structureCondensed Matter PhysicsBiochemistryAtomic and Molecular Physics and OpticsSpectral lineLaser linewidthPerovskite nanocrystalsSemiconductorNanocrystalmicro-photoluminescenceexciton-phonon interactionOptoelectronicsLight emissionDiffusion (business)businesssingle nanocrystalPerovskite (structure)
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Strongly Coupled Coherent Phonons in Single-Layer MoS 2

2019

We present a transient absorption setup combining broadband detection over the visible-UV range with high temporal resolution ($\sim$20fs) which is ideally suited to trigger and detect vibrational coherences in different classes of materials. We generate and detect coherent phonons (CPs) in single layer (1L) MoS$_2$, as a representative semiconducting 1L-transition metal dichalcogenide (TMD), where the confined dynamical interaction between excitons and phonons is unexplored. The coherent oscillatory motion of the out-of-plane $A'_{1}$ phonons, triggered by the ultrashort laser pulses, dynamically modulates the excitonic resonances on a timescale of few tens fs. We observe an enhancement by…

ramanspectroscopyPhononExcitonGeneral Physics and AstronomyFOS: Physical sciences02 engineering and technologyApplied Physics (physics.app-ph)thz phonons010402 general chemistry01 natural sciencesMolecular physicssymbols.namesakephotoinduced bandgap renormalizationtransient absorption spectroscopyUltrafast laser spectroscopyMesoscale and Nanoscale Physics (cond-mat.mes-hall)General Materials Sciencepulsesexciton−phonon interactionPhysicsab initio calculationCondensed Matter - Materials ScienceCondensed Matter - Mesoscale and Nanoscale Physicstransition metal dichalcogenidesgrapheneGeneral Engineeringmonolayer mos2ResonanceMaterials Science (cond-mat.mtrl-sci)excitationmonodynamicsPhysics - Applied Physics021001 nanoscience & nanotechnology0104 chemical sciencesAmplitudeOrders of magnitude (time)coherent phononsexciton-phonon interactionsymbols0210 nano-technologyRaman spectroscopyExcitationACS Nano
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